The Chemical Legacy in Polar Bears

A Ticking Time Bomb in the Arctic

The pristine white of the Arctic wilderness hides a toxic secret, one that accumulates in the body of its top predator.

The polar bear, an iconic symbol of the Arctic, faces a well-documented threat from the climate crisis and melting sea ice. Less visible, but equally insidious, is the burden of industrial chemicals and legacy pollutants that contaminate its body, despite being thousands of miles from any source.

These contaminants journey on wind and water to the Arctic, where they build up in the food web. As the top predator, the polar bear consumes a highly concentrated chemical cocktail, with potential devastating effects on its health and the ecosystem it calls home.

Key Fact: Polar bears can biomagnify pollutants up to 200 times compared to their prey due to their highly efficient lipid assimilation .

The Unseen Invaders: A Glossary of Arctic Contaminants

To understand the threat, we must first identify the key chemical invaders. The Arctic environment acts as a sink for a complex mixture of persistent organic pollutants (POPs), substances that resist environmental breakdown and accumulate in living tissue.

Legacy Contaminants

These are "old" chemicals, banned or severely restricted decades ago but which persist in the environment. Their levels are generally high in polar bears.

  • PCBs: Once used as electrical insulators, these are among the most concerning groups due to their toxicity and persistence.
  • OCPs: This group includes DDE (a breakdown product of DDT) and chlordanes (CHLs), which were widely applied as insecticides.
Emerging and Current-Use Chemicals

These are substances either still in use or recently regulated.

  • BFRs: This includes PBDEs, used in furniture and electronics. Although some formulations have been phased out, they are consistently found in polar bears.
  • PFAS: Also known as "forever chemicals," these are used in non-stick cookware and food packaging. They are stable, persistent, and can have various health effects.
  • HBCD: Another flame retardant, currently with no widespread restrictions.

A Tale of Many Regions: Geographic Hotspots of Contamination

Research on polar bears from 2005 to 2008 revealed that contamination is not uniform across the Arctic. Levels of these pollutants vary significantly, creating distinct geographic hotspots.

East Greenland & Svalbard

Legacy Contaminants: Highest Levels 1

Brominated Flame Retardants: Consistently Found 1

Mercury: Stable, long-term trends 7

Hudson Bay, Canada

Legacy Contaminants: High Levels 1 5

Brominated Flame Retardants: Among highest in Canadian Arctic 5

Alaska

Legacy Contaminants: Lower Levels 1

Brominated Flame Retardants: Consistently Found 1

This east-to-west gradient, with higher levels in the European Arctic, is influenced by ocean currents, atmospheric transport patterns, and the historical use of these chemicals. For example, polar bears from Svalbard show approximately three times higher levels of certain PFAS than those from East Greenland or Canada 7 . Meanwhile, the Barents Sea population, shared by Norway and Russia, carries higher average levels of pollutants like PCBs than bears in Greenland or Arctic Alaska 8 .

The Diet Trap: How Contamination Climbs the Food Chain

The primary route of exposure for polar bears is their diet. As a top predator, it feeds predominantly on ringed seals, which themselves consume fish that have ingested contaminated zooplankton. This creates a perfect storm for biomagnification—the process where contaminant concentrations increase at each successive trophic level.

Zooplankton

Base level contaminants

Fish

Contaminants concentrate

Ringed Seals

Higher concentration

Polar Bears

Maximum concentration

99.5%

Lipid assimilation efficiency in polar bears

200x

Biomagnification potential in polar bears compared to prey

A 2024 study unveiled just how astonishingly efficient polar bears are at biomagnifying pollutants. The research introduced a non-invasive method to study this process in zoo-housed bears, revealing two key factors :

  1. High-Fat Diet: Seal blubber is rich in lipids, which are excellent at absorbing and storing these fat-soluble chemicals.
  2. Extreme Lipid Assimilation: Polar bears have a digestive efficiency of up to 99.5% for lipids. When they digest the fat from their prey, the contaminants are not excreted but are transferred almost completely into their own bodies.

This combination results in a biomagnification capability—the potential for a chemical to concentrate in the predator compared to its prey—that can be up to 200 times . This means a chemical can be 200 times more concentrated in the polar bear than in the seal it ate.

A Vulnerable Future: Climate Change Complicates the Picture

Climate change is not a separate threat; it intensifies the problem of pollution. As the Arctic warms at an alarming rate, it alters the very environment that governs how polar bears interact with these toxins.

Sea Ice Loss and Fasting

Longer ice-free seasons force polar bears to spend more time on land, fasting and living off their fat reserves. This fat breakdown releases stored contaminants into their bloodstream, increasing exposure to vital organs 7 8 .

Diet Shifts

With less access to seals, some bears are turning to alternative food sources like bird eggs, reindeer, and vegetation. While this may temporarily reduce the intake of some marine-sourced contaminants, it also leads to poorer body condition and may introduce other pollutants 8 .

Re-mobilization of Legacy Pollutants

Melting glaciers and permafrost may be re-releasing legacy contaminants that were trapped for decades, creating a second wave of pollution 4 .

A Path Forward

The story of flame retardants and legacy contaminants in polar bears is a powerful reminder that our actions have far-reaching consequences. The toxins used decades ago, or in products far from the Arctic, continue to haunt this remote ecosystem.

The good news is that regulation works, as shown by the declining levels of regulated PCBs and PBDEs. However, the emergence of new chemicals and the unsettling resurgence of others demand continued vigilance. Protecting the polar bear requires a dual strategy: urgent action on climate change to preserve their sea-ice habitat and robust global policies to eliminate the production and release of persistent toxic chemicals. The health of the Arctic's top predator is a barometer for the health of the entire planet.

To follow the latest research and monitoring data, you can explore resources provided by the Norwegian Polar Institute's MOSJ (Environmental monitoring of Svalbard and Jan Mayen) 7 .

References